There are five deaneries in the Diocese. They are Bibiani Deanery, Wiawso Deanery, Asafo Deanery, Enchi Deanery and Adjoafua Deanery. There are 29 Parishes and 2 Rectorates in the Diocese. Find below the various Parishes grouped on deanery basis:
| BIBIANI DEANERY St. Teresa Parish, Bibiani Christ the King Parish, Kyekyewere St. Anthony Parish, Chirano St. Francis Xavier Parish, Awaso Immaculate Conception Rectorate, Atronsu St. Benedict Parish, Bekwai WIAWSO DEANERY St. Joseph Cathedral, Wiawso St. Mary Parish, Dwinase St. Andrew Parish, Aboduam St. John the Baptist Rectorate, Datano St. Joseph Parish, Nsawora | ASAFO DEANERY St. Agatha Parish, Asafo St. Joseph Parish, Afere St. Augustine Parish, Boako St. Anthony Parish, Juaboso St. Matthew Parish, Bodi St. Peter Parish, Asawinso St. Francis Xavier Parish, Bonsu Nkwanta St. Patrick Rectorate, Boinzan |
| ENCHI DEANERY Immaculate Conception Parish, Enchi St. Michael Parish, Dadieso St. Theresa Parish, New Yakase St. Matthew Parish, Akontombra St. Alfred Parish, Jema St. Paul Parish, Boinso | ADJOAFUA DEANERY St Paul Parish, Adjoafua St. Theresa Parish, Yawmatwa Blessed Virgin Mary Parish, Adabokrom St Anthony Parish, Oseikojokrom St. Anthony Parish, Essam St. Ambrose Parish, Kwamebikrom |
With the Parish centres inclusive, there are 324 stations in the Diocese. 49 stations are in the Bibiani Deanery, 52 are in the Wiawso Deanery, 85 are in the Asafo Deanery, 75 are in Enchi Deanery while the remaining 63 are in the Adjoafua Deanery. The various stations in the Diocese are found below:
| TOWN | PATRON SAINT | YEAR OF FOUNDATION |
| BIBIANI (Parish Centre) | St. Theresa | 1900 (1912-Creation as a Parish) |
| ABODUABO | St. John | 2007 |
| ADUKROM | St. Gabriel | 1956 |
| ADUPURI | St. Pius | 1954 |
| AFAMU | St. Peter | 1952 |
| ANHWIASO | St. Anthony | 1983 |
| CHINE | St. Luke | 2006 |
| DEBISO-BREMAN | St. Paul | 1945 |
| DOMINIBO II | St. Augustine | 1940 |
| KUNKUMSO | St. Anthony | 1978 |
| PATABOSO | St. Patrick | 1940 |
| TANOSO | St. Peter | 1954 |
| WENCHI | St. Joseph | 1927 |
| CHIRANO (Parish Centre) | St. Anthony | 1927 (2020 – creation as a Parish) |
| AKAASO | St. Anna | 1937 |
| AKOTI | St. Matthew | 1978 |
| ANYINASE | St. Francis Xavier | 1997 |
| KWAWKROM | St. Philip | 1950 |
| NTAKAM | St. Michael | 1991 |
| SUBIRI | St. Augustine | 1942 |
| SURANO | St. Peter | 1954 |
| KYEKYEWERE(Parish Centre) | Christ the King | 2020 |
| NZEMA-NKWANTA | St. Joseph | 1952 |
| BASEENGELLE | St. Peter | 1982 |
| LINESO | St. Mark | 1952 |
| BEKWAI (Parish Centre) | St. Benedict | 1927 (1991-creation as a Parish) |
| ABONIDUA | St. Peter | |
| ADIEMBRA | St. Martin | 1943 |
| AKAASU | St. Joseph | 1964 |
| ALATA | St. Ambrose | 1940 |
| AMPEMKROM | St. Elizabeth | 1932 |
| ANKAMATENG | St. Francis | 2016 |
| ASHIAM | St. Mathew | 1942 |
| BANGROMISA | St. Martha | 1941 |
| BEDI | St. Paul | 2001 |
| HUMJIBRE | St. Anthony | 1927 |
| KOJINA | St. George | 1943 |
| KWAKUBOA | St. Paul | 1991 |
| KYEIKROM | St. John the Baptist | 1990 |
| MUOHO | St. Francis Xavier | 1928 |
| NYETINA | St. Joseph | 1943 |
| NKYENSIM | Holy Trinity | 2016 |
| SORANO | St. Mary | 2001 |
| AWASO (Parish Centre) | St. Francis Xavier | 1940 (2011- Erection as a Rectorate) (2015- Creation as a Parish) |
| ASAWINSO | St. Philip | 1990 |
| BEPOSO | St. Peter | 1940 |
| NKATIESO | Blessed Virgin Mary | 1950 |
| SUBIRI NKWANTA | St. Joseph | 1942 |
| ATRONSU (Rectorate) | Immaculate Conception | 1917 (2018 – Erection as a Rectorate) |
| DWINASE (Parish Centre) | St. Mary | 1949 (2000 – Creation as a Rectorate) (2010 – Creation as a Parish) |
| TANOSO | St. Joseph | 2015 |
| NSUENSUA | St. Henry | 1950 |
| AHOKWAA | St. Peter | 1950 |
| SUHENSO | St. Patrick | 1980 |
| ANGLO | St. Stephen | 1930 |
| AYIREKROM | St. Anthony | 1952 |
| KYEAMEKROM | St. Augustine | 2000 |
| DATANO (Rectorate) | St. John the Baptist | 1950 (2018 – Creation as a Rectorate) |
| WIAWSO (Cathedral) | St. Joseph | 1927 (1964 – Erection as a Parish) |
| ABOBOYAA | St. John | 2006 |
| AHWIAM | St. Francis | 2009 |
| OLD ADIEMBRA | St. Joseph | 2006 |
| AMAFIE | St. Peter Canisius | 1942 |
| BOSOMOISO | St. Theresa | 1940 |
| NSAWORA (Parish Centre) | St. Joseph | 1942 (2015 – Creation as a Parish) |
| ACKAAKROM | St. Charles | 1978 |
| AGYEMAN CAMP | ———- | ———- |
| AHWIAFUTU | St. Peter | 1999 |
| APROGYA | St. James | 1989 |
| APRUTU | St. James | 1950 |
| ASANTEMAN | St. Augustine | 1977 |
| ASIEKROM | St. John the Baptist | 1981 |
| ATTAKROM | St. Joseph | 1970 |
| AYISAKROM | St. Augustine | 1985 |
| BETENASE | St. Theresa | 2000 |
| BOPA | St. Peter | 1939 |
| CHOROCHORI | St. Michael | 1975 |
| DOMI | St. Titus | 1955 |
| FAWOKABRA | St. Blaise | 1953 |
| FORDJOUR | St. Lucy | 2002 |
| KOFIKROM | St. Mary | 1986 |
| KOJOKROM | St. Lawrence | 1940 |
| KORDJOUR | St. Peter | 2002 |
| KRAMOKROM | St. Paul | 1951 |
| KWAJOBIKROM | St. Dominic | 2004 |
| LIMAN | St. Williams | 1992 |
| NEWSAPA | St. Anthony | 2002 |
| NKWADUM | St. Theresa | 1940 |
| NYAMENAE | St. Theresa | 1940 |
| SHELL | 2005 | |
| WAWSAMPO | St. Mathew | 1978 |
| WURUWURU | St. Anthony | 2005 |
| YAWKROM | St. Anthony | 1952 |
| ABODUAM | St Andrew | 1927 (2003 – Erection as a Rectorate)(2010 – Creation as a Parish) |
| AHWIAA | St. John | 1947 |
| APPIAKROM | St. Thomas | 1945 |
| EWIASE | St. Francis | —- |
| FUTA | St. Barnabas | —- |
| NTRENTRESO | Corpus Christi | 2017 |
| PENAKROM | St. James | —– |
| PABOASE | St. Theresa | —— |
| ASAFO (Parish Centre) | St Agatha | *1924 |
| ACHEACHAEN | St. Michael | 1971 |
| KUNUMA | St. Francis | 1981 |
| AFERE (Parish Centre) | St. Joseph | 1924 (1991 – Creation as a Parish) |
| TIKOBO | St. Matthew | 1973 |
| BENUMSUO | St. John | 1993 |
| AMOAYA | St. Francis | 1931 |
| DATANO | St. Joseph | 1938 |
| KWASIKROM | St. Martha | 1939 |
| ANTOBIA | St. Joseph | 1936 |
| PATAKRO | St. Joseph | 1935 |
| BESEASE | St. Clara | 1998 |
| BOKABO | St. Francis | 1938 |
| SAMANSUO | St. Juan | 2001 |
| KRAYAWKROM | St. Paul | 1936 |
| KOTOSH | St. John | 1992 |
| TUMANTU | St. John | 1999 |
| BOAKO (Parish Centre) | St. Augustine | 1931 (2001 – Erection as a quasi-parish)(2004 – Creation as a Parish) |
| AYINABRIM | St. Albert | 1974 |
| MILE 5 | St. Peter | 1987 |
| ABRABRA | St. Peter | 1954 |
| NKONYA | St. Paul | 1984 |
| SUI | St. James | 1940 |
| CAMP | St. Williams | 1939 |
| PUNIKROM | St. Maira Goretti | 1940 |
| AKURAFU | St. Paul | 1972 |
| AMPROMPE | St. John the Baptist | 1985 |
| SWANZYKROM | St. Nicholas | 1985 |
| PEASE | ————- | ——- |
| JUABOSO | St. Anthony | 1936 (2008 – Creation as a Parish) |
| ABONO | St. Elizabeth | —— |
| ADIEMBRA | St. Mary | 1953 |
| DOMI | St. Stephen | 1940 |
| ELLUBO | St. Stephen | 1953 |
| JUABOSO NKWANTA | St. Charles | 1970 |
| MANTUKWA | St. Cecilia | 1988 |
| METEMANO | St. Cecilia | 1952 |
| PROSO | St. John | 1936 |
| BOINZAN (Rectorate) | St. Patrick | 1940 (2015 – Erection as a Rectorate) |
| ABROKOFE | St. Philomena | 1930 |
| KWAWKROM | St. Anna | 1959 |
| BODI (Parish Centre) | St. Matthew | (2013 – Creation as a Parish) |
| DENCHEMOASUE | St. Joseph | ——— |
| KAMA | St. George | ——— |
| KWAFUKAA | St. Anthony | ——— |
| AHIBENSO | St. Mary Magdalene | ——— |
| L.L.L | St. Paul | ——— |
| APPIENTI | St. Patrick | ——— |
| MAME AMA | St. Dominic | ——— |
| PUAKROM | Christ the King | ——— |
| NKRUMAHKROM | St. John of God | ——— |
| KOAKROM | St. Michael | ——— |
| ABISAWIE | St. Mary | ——— |
| ATTABOKA | ———– | ——— |
| BOMPLEX | ———- | ——— |
| ASAWINSO (Parish Centre) | St. Peter | *1930 (….. creation as a Parish) |
| ABOAGYEKROM | St. Anthony | 2004 |
| AGYEMADIEM | St. Clement | 1940 |
| BARRIER | St. Francis | |
| BENCHEMA | St. Albert | 1925 |
| ESSAKROM | St. Raphael | 1940 |
| KANTANKRUBO | St. Mark | 1941 |
| KOJINA | St. Gabriel | 1940 |
| NSINSEM | St. Anthony | 1940 |
| SAYERANO | St. Peter | 1932 |
| 290 | St. Paul | 1978 |
| BONSU NKWANTA (Par. C) | St. Francis Xavier | 1986 (2015 – Creation as a Parish) |
| ABOBOYAA | St. John | 1994 |
| ADDAIKROM | St. Peter | 1978 |
| ADWUMAWURA | St. Charles | 1984 |
| AFRICA | St. Joseph | 1996 |
| ANHWEAFUTU | St. George | 1985 |
| APAAKROM | St. Stephen | 1983 |
| FRATRALINE | St. Nicholas | 1982 |
| GYATO | St. Joseph | 1982 |
| HWEMEHAA | St. Francis | 1999 |
| KEFASS | St. Peter | 1998 |
| KRAKU KYERE | St. Francis | 1989 |
| MANHYIA | St. Joseph | 1993 |
| MINTAKROM | St. Patrick | 1976 |
| NEW BEREKUM | St. Anthony | 1982 |
| NKYENSEKOKOO | St. Mary | 2014 |
| NTONSUE | St. Ambrose | 1983 |
| NYAMEBEKYERE | St. John | 1998 |
| TAWIAKROM | St. Vincent de Paul | 1983 |
| YAW BREFO | St. Paul | 2012 |
| ADJOAFUA (Parish Centre) | St. Paul | 1947 |
| BEREKROM | St. Stephen | 1992 |
| KOMIAMAA | St. Lawrence | 1934 |
| MAFIA | St. Bartholomew | 1941 |
| ASUONTAA | St. Benedict | 1947 |
| NKRA | St. Andrew | 1975 |
| ASEMPANEYE | St. John | —– |
| DOMINEBO | St. John | —– |
| ELLUOKROM | St. Mary | 1957 |
| KWAMETAWIAKROM | St. Mathew | 1946 |
| YEREPIEMSO | St. Paul | 1988 |
| AMANHYIA | St. Francis | 1978 |
| BIANO | St. Peter | 1947 |
| ETESO | St. Agatha | 1934 |
| ASANTEMAN | St. Mathew | 1978 |
| NEW AGOGO | St. Anna | 1980 |
| PAPAASE | St. Andrew | 1960 |
| OSEIKOJOKROM (Par. Centre) | St. Anthony | 1970 |
| ABOTARE YE | St Paul | 1989 |
| AMOAKROM | St. Joseph | 1975 |
| KAKENABO | St. Andrew | 1980 |
| KOJOAB A | St. Martha | 1986 |
| SEKYEREKROM | St. Peter | 1981 |
| TEACHERKROM | ———– | ———– |
| YAWMATWA (Parish Centre) | St. Theresa of the Child Jesus | 1940 (1996-Creation as a Parish) |
| AMANGOASE | St. Anthony | 1968 |
| BEPOSO | St. Paul | 1978 |
| KAASE | St. Isidore | 1960 |
| KWAME DAPAAKROM | St. Anthony | 1990 |
| NKWANTKESE | St. Francis | 1986 |
| NSONWAKROM | St. Francis | 1973 |
| YAWMATWA NKWATA | St. Paul | 1992 |
| PILLA 34 | St. John the Baptist | 2015 |
| ESSAM (Parish Centre) | St. Anthony | 1936 (2008 – Creation as a Parish) |
| DEBISO | St. Paul | —— |
| ASIKUMA | St. Cecilia | 1930 |
| DEBISO NEW TOWN | St. Joseph | 2003 |
| KUNKUMSO | St. Michael | 1991 |
| ASUOPRI | St. Francis | 1967 |
| KWAMEBIKROM (Par. Centre) | St. Ambrose | 1933 (2018 – Creation as a Parish) |
| AKAATISO | St. Michael | 1983 |
| KOOFIEPONKOR | St. Paul | 1972 |
| KOOTOKROM | St. John | 1985 |
| KWAME DRIVER | St Peter | 1982 |
| KWASI NKRUMAH | St John the Baptist | 1985 |
| NEW TEWOBAABI | St Joseph | 1989 |
| NEW WENCHI | St. Michael | 1989 |
| NTENSERE | St. Peter | —– |
| SUNSUMPE | St Anthony | 1984 |
| TEACHERKROM | St Joseph | —— |
| ADABOKROM (Parish Centre) | Blessed Virgin Mary | 1944 |
| ACHIASE | St. Stephen | 1968 |
| AMADUKROM | St. Anthony | 1983 |
| AMOATENKROM | St Joseph | 1964 |
| ASEMINYINAKROM | St. Thomas | 2004 |
| BAMOAH | St. Cecilia | 2007 |
| CAMP 15 | St Peter | 1983 |
| FOSUKROM | St. Anthony | 1954 |
| KWABENA NKETAA | St Patrick | 1977 |
| KWASAREKROM | St Joseph | 1954 |
| NYAMEBEKYERE | St Matthias | 2005 |
| SEBEBIA | St Joseph | 1952 |
| SIKAFREMOGYA | St Joseph | 1952 |
| ENCHI (Parish Centre) | Immaculate Conception | 1916 |
| NYANKAMAM | St. Francis | 1935 |
| KRAMOKROM | St. Mary | 1953 |
| NKWANTA | St. Peter | 1916 |
| ACHIMFO | St. Augustine | 1967 |
| EBIKWAKROM | St. Francis | 1985 |
| NEW GYASIKROM | St. Dominic | 1987 |
| JENSUE | St. Anthony | 1953 |
| ADJAKAA | St. Monica | 1922 |
| ABOCHIA | St. Theresa | 1924 |
| NYANEY CAMP | St. Paul | 1976 |
| YIWABRA TOWN | St. Monica | 1947 |
| YIWABRA JUNC. | St. Francis | 1941 |
| ADJOUM | St. Joseph | 1917 |
| DISUE ANO | St. Joseph | 1940 |
| PAPUESO | St. Mary | 1980 |
| NYMEKYEREKROM | St. John | 1984 |
| CAMP 4 | St. Peter | 1990 |
| AQUAE ALLAH | St. Anthony | 1993 |
| ASUOKLO | St. Francis | 1975 |
| ANGUNZU | St. Anthony | 1982 |
| MILE 4 | St. John | 1985 |
| BONOKESE | Christ the King | 1976 |
| ABOTAREYE | St. Peter | 1982 |
| CHARLESKROM | St. John | 1985 |
| ASANTEKROM | St. Andrew | 1985 |
| AKYIRIFIKROM | St. Paul | 2003 |
| NEW YAKASI (Par. Centre) | St. Theresa of the Child Jesus | 1955 (2009 – Creation as a Parish) |
| ADONIKROM | Christ the King | 1971 |
| AHWIAFUTU | St. Francis | 1984 |
| AFODOA | St. Francis | 1971 |
| AHWIAFUTU | St. Augustine | 1984 |
| AKONTOMBRA | St. Joseph | 1982 |
| DABIASEM | St. Joseph | 1986 |
| MOTTOSO | St. Peter | —— |
| OLD YAKASI | St. Leo | 1944 |
| SUSAN | St. Catherine | 2004 |
| TECHIMAN | St. Peter | 1978 |
| AKONTOMBRA (Par. Centre) | St. Matthew | ——(2009-Creation as a Parish) |
| YAMFO | St. Helena | —— |
| ESSASE | St. Martin | 1970 |
| AHWIAFUTU | St. Matthew | —— |
| KOJOBIKROM | St. Mary | 2001 |
| ABRONAHIA | St. John the Baptist | —— |
| KABIESUE | St. John the Baptist | 1985 |
| BAWAKROM | St. Matthew | 1987 |
| BRONIKROM | St. Anna | 1984 |
| NYAMEBEKYERE | John the Baptist | —– |
| BOKASO | St. Mary | 2000 |
| TANOKROM | St. Paul | 2009 |
| BOSSOMPEM | St. Theresa | —— |
| DADIESO (Parish Centre) | St. Michael | 1937 |
| ANTOKROM | St. Peter | 1984 |
| KARLO | St. Stephen | 1949 |
| KWABLA NARTEY | St. Peter | 1976 |
| KWAKU AMOAKROM | St. Paul | 1979 |
| KWABENAKROM | St. Paul | 1983 |
| KWASUO | St. John | 1983 |
| MMOFRAMFADWENE | St Louis | 1992 |
| NYAMEBEKYERE | St. Anthony | 1979 |
| PETERKROM | St. Patrick | 1980 |
| SUIANO | St. Peter | 1996 |
| SUIBO | St. Paul | 1998 |
| TAWIAKROM | St. Anthony | 1984 |
| JEMA (Parish Centre) | St. Alfred | 1916 (2008-Creation as a Parish) |
| ANOKROM | St. James | 2008 |
| ASEMKROM | St. Andrews | 1916 |
| NGAKANI | St. John | 1991 |
| BOINSO (Parish Centre) | St. Paul | 1916 (2018 – Creation as a Parish) |
| ALATAKROM | St Peter and Paul | 1985 |
| AKWAKOM | ||
| AMONIE | St. Charles | 1917 |
| GYASIKROM | St. Michael | 2015 |
| KWAWU | St. Francis | 1916 |
| NYAMEBEKYERE | St. Francis | 2008 |
| OMANPE | St. Gregory | 1916 |
| SEWUM | St. Albert | 1980 |